换一批Combined approach using capillary electrophoresis and NMR spectroscopy for an understanding of enantioselective recognition mechanisms by cyclodextrins.
摘要：
This tutorial review describes the contribution of chiral capillary electrophoresis in combination with other instrumental techniques, especially nuclear magnetic resonance spectroscopy, to a better understanding of the chiral recognition mechanisms by cyclodextrins. Aspects such as affinity pattern of enantiomers towards various cyclodextrins as well as the stoichiometry of the resulting complexes, the equilibrium constants and the structure of complexes are addressed. In addition to the aforementioned techniques, the usefulness of complementary instrumental and molecular modeling techniques for an understanding of the chiral recognition mechanisms of cyclodextrins is also illustrated.
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作者：
Bezhan,Chankvetadze [1]
作者单位：
Molecular Recognition and Separation Science Laboratory
[1]
School of Chemistry
[2]
Tbilisi State University
[3]
Chavchavadze Ave 1
[4]
380028 Tbilisi
[5]
Georgia. bezhan_chankvetadze@yahoo.com
[6]
期刊：
主题词：
环糊精类(Cyclodextrins);电泳, 毛细管(Electrophoresis, Capillary);磁共振波谱学(Magnetic Resonance Spectroscopy);模型, 分子(Models, Molecular);分子构象(Molecular Conformation);立体异构现象(Stereoisomerism)
DOI：
10.1039/b111412n
PMID：
15280966
发布时间：
2005-11-16
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