换一批Continuous reactions in supercritical carbon dioxide: problems, solutions and possible ways forward.
摘要：
This Tutorial Review focuses on supercritical carbon dioxide (scCO(2)), and discusses some of the problems that have frustrated its wide use on an industrial scale. It gives some recent examples where strategies have been developed to reduce the energy requirements, including sequential reactions and gas-expanded liquids. It then describes a number of cases where scCO(2) offers real chemical advantages over more conventional solvents, for example by controlled phase separation, tunable selectivity, oxidation and on-line analysis and self-optimisation. Overall, this review indicates where scCO(2) could deliver value in the future.
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作者：
Xue,Han [1]
;
Martyn,Poliakoff [2]
作者单位：
The School of Chemistry
[1]
The University of Nottingham
[2]
Nottingham
[3]
NG7 2RD
[4]
UK.
[5]
期刊：
《Chemical Society reviews》
2012年41卷4期1428-36页
主题词：
二氧化碳(Carbon Dioxide);催化作用(Catalysis);绿色化学技术(Green Chemistry Technology);离子液体(Ionic Liquids);异构现象(Isomerism);氧化还原(Oxidation-Reduction)
DOI：
10.1039/c2cs15314a
PMID：
22246245
发布时间：
2013-11-21
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