换一批Synthesis, structure and reactivity of rare-earth metal complexes containing anionic phosphorus ligands.
摘要：
A comprehensive review of structurally characterized rare-earth metal complexes containing anionic phosphorus ligands is presented. Since rare-earth elements form hard ions and phosphorus is considered as a soft ligand, the rare-earth metal phosphorus coordination is regarded as a less favorite combination. Three classes of phosphorus ligands, (1) the monoanionic organophosphide ligands (PR2(-)) bearing one negative charge on the phosphorus atom; (2) the dianionic phosphinidene (PR(2-)) and P(3-) ligands; and (3) the pure inorganic polyphosphide ligands (Pn(x-)), are included here. Particular attention has been paid to the synthesis, structure, and reactivity of the rare-earth metal phosphides.
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作者：
Tianshu,Li [1]
;
Sabrina,Kaercher [2]
;
Peter W,Roesky [3]
作者单位：
Institut für Anorganische Chemie
[1]
Karlsruhe Institute of Technology (KIT)
[2]
Engesserstrasse 15
[3]
76131 Karlsruhe
[4]
Germany. roesky@kit.edu.
[5]
期刊：
DOI：
10.1039/c3cs60163c
PMID：
23945727
发布时间：
2013-12-03
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