Asymmetric synthesis of 2,3-dihydrofurans and of unsaturated bicyclic tetrahydrofurans through alpha-elimination and migratory cyclization of silyloxy alkenyl aminosulfoxonium salts. Generation and intramolecular O,Si-bond insertion of chiral disubstituted beta-silyloxy alkylidene carbenes.
第一作者:
Hans-Joachim,Gais
第一单位:
Institut für Organische Chemie der Rheinisch-Westfälischen Technischen Hochschule (RWTH) Aachen, Prof.-Pirlet-Strasse 1, D-52056 Aachen, Germany. Gais@RWTH-Aachen.de
作者:
DOI
10.1021/ja030501v
PMID
15080690
发布时间
2004-04-14
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