Gauging the relative oxidative powers of compound I, ferric-hydroperoxide, and the ferric-hydrogen peroxide species of cytochrome P450 toward C-H hydroxylation of a radical clock substrate.
作者:
主题词
催化作用(Catalysis);细胞色素P450酶系统(Cytochrome P-450 Enzyme System);正铁化合物(Ferric Compounds);过氧化氢(Hydrogen Peroxide);氢离子浓度(Hydrogen-Ion Concentration);羟基化(Hydroxylation);模型, 分子(Models, Molecular);氧化还原(Oxidation-Reduction);热力学(Thermodynamics)
DOI
10.1021/ja056328f
PMID
16402834
发布时间
2013-11-21
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