Efficient asymmetric synthesis of P-chiral phosphine oxides via properly designed and activated benzoxazaphosphinine-2-oxide agents.

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作者： Zhengxu S,Han ^[1] ; Navneet,Goyal ; Melissa A,Herbage ; Joshua D,Sieber ; Bo,Qu ; Yibo,Xu ; Zhibin,Li ; Jonathan T,Reeves ; Jean-Nicolas,Desrosiers ; Shengli,Ma ; Nelu,Grinberg ; Heewon,Lee ; Hari P R,Mangunuru ; Yongda,Zhang ; Dhileep,Krishnamurthy ; Bruce Z,Lu ; Jinhua J,Song ; Guijun,Wang ; Chris H,Senanayake

作者单位： Department of Chemical Development, Boehringer Ingelheim Pharmaceuticals Inc., 900 Old Ridgebury Road, P.O. Box 368, Ridgefield, Connecticut 06877, USA. steve.han@boehringer-ingelheim.com ^[1]

主题词环磷氧化物(Cyclic P-Oxides);配体(Ligands);分子结构(Molecular Structure);磷化氢类(Phosphines);立体异构现象(Stereoisomerism)

DOI 10.1021/ja312352p

PMID 23369026

发布时间 2016-11-25

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准确一般字义偏差语意偏离译文作用小提交