An unexpectedly lichenase-stable hexasaccharide from cereal, horsetail and lichen mixed-linkage β-glucans (MLGs): implications for MLG subunit distribution.
第一作者:
Thomas J,Simmons
第一单位:
The Edinburgh Cell Wall Group, Institute of Molecular Plant Sciences, The University of Edinburgh, The King's Buildings, Edinburgh EH9 3JH, UK.
作者:
关键词
(G4)(n)G3G where n=0(G4)(n)G3G where n=1(G4)(n)G3G where n=26xAIRCOSYCSSFCerealsDPEquisetumG4G3G etc.GPCGlcolHSQCK(av)LichenanLichenaseMLGMLG hexasaccharide not conforming to the sequence type (G4)(n)G3GMLG oligosaccharideMLG2MLG3MLG4MLGONMRNOESYPADPyAW/CBTFATOCSYXEGalcohol-insoluble residuechemical-shift-selectivecorrelation spectroscopydegree of polymerisationelution volume on GPC relative to glucose (K(av)=1) and dextran (K(av)=0)gel-permeation chromatographyglucitolheteronuclear single quantum spectroscopymixed-linkage (1→3),(1→4)-β-d-glucannuclear Overhauser spectroscopypulsed amperometric detectorpyridine/acetic acid/water (1:1:98 by volume, pH ~4.7) containing 0.5 (w/v) chlorobutanoltotal correlation spectroscopytrifluoroacetic acidxyloglucan endoglucanaseβ-Glucanβ-d-glucose residues interlinked by (1→4) or (1→3) bonds
医学主题词
子囊菌纲(Ascomycota);芽孢杆菌属(Bacillus);生物制品(Biological Products);碳水化合物序列(Carbohydrate Sequence);木贼属(Equisetum);糖苷水解酶类(Glycoside Hydrolases);大麦属(Hordeum);地衣(Lichens);寡糖类(Oligosaccharides);植物提取物(Plant Extracts);底物特异性(Substrate Specificity);β葡聚糖类(beta-Glucans);β葡糖苷酶类(beta-Glucosidase)
DOI
10.1016/j.phytochem.2013.08.003
PMID
24025426
发布时间
2025-05-29
- 浏览80
Phytochemistry
322-32页
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