Spectroscopic capture and reactivity of a low-spin cobalt(IV)-oxo complex stabilized by binding redox-inactive metal ions.

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作者： Seungwoo,Hong ^[1] ; Florian Felix,Pfaff ^[2] ; Eunji,Kwon ^[1] ; Yong,Wang ^[3] ; Mi-Sook,Seo ^[1] ; Eckhard,Bill ^[4] ; Kallol,Ray ^[2] ; Wonwoo,Nam ^[1]

作者单位： Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea. ^[1] Humboldt-Universität zu Berlin, Department of Chemistry, Brook Taylor Strasse 2, 12489 Berlin, Germany. ^[2] State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China. ^[3] Max-Plank-Institut für chemische Energiekonversion, Mülheim an der Ruhr (Germany). ^[4]

关键词 Lewis acids cobalt oxo ligands oxygenation redox tautomerization

主题词钴(Cobalt);配位络合物(Coordination Complexes);离子(Ions);金属(Metals);氧化还原(Oxidation-Reduction);氧(Oxygen);量子论(Quantum Theory)

DOI 10.1002/anie.201405874

PMID 25081948

发布时间 2023-11-11

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