Rhodium(III)-Catalyzed ortho C-H Heteroarylation of (Hetero)aromatic Carboxylic Acids: A Rapid and Concise Access to π-Conjugated Poly-heterocycles.

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作者： Xurong,Qin ^[1] ; Xiaoyu,Li ^[1] ; Quan,Huang ^[1] ; Hu,Liu ^[1] ; Di,Wu ^[1] ; Qiang,Guo ^[1] ; Jingbo,Lan ^[2] ; Ruilin,Wang ^[3] ; Jingsong,You ^[4]

作者单位： Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (PR China). ^[1] Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (PR China). jingbolan@scu.edu.cn. ^[2] College of Materials Science and Engineering, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (PR China). ^[3] Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064 (PR China). jsyou@scu.edu.cn. ^[4]

关键词 C?H activation conjugation cross-coupling heterocycles rhodium

主题词碳(Carbon);羧酸类(Carboxylic Acids);催化作用(Catalysis);杂环化合物(Heterocyclic Compounds);氢(Hydrogen);铑(Rhodium);立体异构现象(Stereoisomerism)

DOI 10.1002/anie.201501982

PMID 25917223

发布时间 2015-06-02

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