Reversible α-Hydrogen and α-Alkyl Elimination in PC(sp(3))P Pincer Complexes of Iridium.

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作者： Klara J,Jonasson ^[1] ; Alexey V,Polukeev ^[1] ; Rocío,Marcos ^[2] ; Mårten S G,Ahlquist ^[2] ; Ola F,Wendt ^[3]

作者单位： Centre for Analysis and Synthesis, Department of Chemistry, Lund University, PO Box 124, 22100 Lund (Sweden). ^[1] Division of Theoretical Chemistry & Biology, School of Biotechnology, KTH Royal Institute of Technology, 10691 Stockholm (Sweden). ^[2] Centre for Analysis and Synthesis, Department of Chemistry, Lund University, PO Box 124, 22100 Lund (Sweden). ola.wendt@chem.lu.se. ^[3]

关键词 density functional calculations elimination iridium kinetics pincer complexes

主题词配位络合物(Coordination Complexes);结晶学, X线(Crystallography, X-Ray);氢(Hydrogen);铱(Iridium);分子构象(Molecular Conformation);量子论(Quantum Theory);热力学(Thermodynamics)

DOI 10.1002/anie.201503593

PMID 26118858

发布时间 2015-07-29

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