Characterizing the Solvated Structure of Photoexcited [Os(terpy)₂](2+) with X-ray Transient Absorption Spectroscopy and DFT Calculations.

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作者： Xiaoyi,Zhang ^[1] ; Mátyás,Pápai ^[2] ; Klaus B,Møller ^[3] ; Jianxin,Zhang ^[4] ; Sophie E,Canton ^[5]

作者单位： X-ray Sciences Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, USA. xyzhang@aps.anl.gov. ^[1] Department of Chemistry, Technical University of Denmark, Kongens Lyngby DK-2800, Denmark. papai@kemi.dtu.dk. ^[2] Wigner Research Centre for Physics, Hungarian Academy of Sciences, "Lendület" (Momentum) Femtosecond Spectroscopy Research Group, P.O. Box 49, Budapest H-1525, Hungary. papai@kemi.dtu.dk. ^[3] Department of Chemistry, Technical University of Denmark, Kongens Lyngby DK-2800, Denmark. klaus.moller@kemi.dtu.dk. ^[4] School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China. zjx1980@126.com. ^[5] Deutsches Elecktronen Synchrotron (DESY), Notkestr. 85, Hamburg 22607, Germany. secanton2012@gmail.com. ^[6] IFG Structural Dynamics of (Bio)Chemical Systems, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, Goettingen D-37077, Germany. secanton2012@gmail.com. ^[7]

关键词 X-ray transient absorption spectroscopy excited-state osmium polypyridyl complex