Asymmetric Sequential Cu-Catalyzed 1,6/1,4-Conjugate Additions of Hard Nucleophiles to Cyclic Dienones: Determination of Absolute Configurations and Origins of Enantioselectivity.

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作者： Charlie,Blons ^[1] ; Marie S T,Morin ^[1] ; Thibault E,Schmid ^[1] ; Thomas,Vives ^[1] ; Sophie,Colombel-Rouen ^[1] ; Olivier,Baslé ^[1] ; Thibault,Reynaldo ^[2] ; Cody L,Covington ^[3] ; Stéphanie,Halbert ^[4] ; Sean N,Cuskelly ^[5] ; Paul V,Bernhardt ^[5] ; Craig M,Williams ^[5] ; Jeanne,Crassous ^[2] ; Prasad L,Polavarapu ^[3] ; Christophe,Crévisy ^[1] ; Hélène,Gérard ^[4] ; Marc,Mauduit ^[1]

作者单位： Ecole Nationale Supérieure de Chimie de Rennes, CNRS UMR 6226, 11 allée de Beaulieu, CS 50837, 35708, Rennes Cedex 7, France. ^[1] Université de Rennes 1, CNRS, UMR 6226, Campus de Beaulieu, 35042, Rennes Cedex, France. ^[2] Department of Chemistry, Vanderbilt University, Nashville, TN, 37235, USA. ^[3] Sorbonne Universités, UPMC Univ Paris 06, CNRS, Laboratoire de Chimie Théorique CC 137, 4, place Jussieu F., 75252, Paris Cedex 05, France. ^[4] School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD 4072, Australia. ^[5]

关键词 asymmetric catalysis circular dichroism configuration determination conjugate addition copper

DOI 10.1002/chem.201606034

PMID 28370488

发布时间 2018-02-02

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