The evaluation of the hydrophilic-hydrophobic interactions and their effect in water-methanol solutions: A study in terms of the thermodynamic state functions in the frame of the transition state theory.

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作者： Francesco,Mallamace ^[1] ; Carmelo,Corsaro ^[2] ; Sveva,Longo ^[3] ; Sow-Hsin,Chen ^[4] ; Domenico,Mallamace ^[5]

作者单位： MIFT Department, University of Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy; Institute for Chemical and Physical Processes IPCF-CNR of Messina, Viale F. Stagno d'Alcontres 37, 98158 Messina, Italy; NSE Department, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. ^[1] MIFT Department, University of Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy; Institute for Chemical and Physical Processes IPCF-CNR of Messina, Viale F. Stagno d'Alcontres 37, 98158 Messina, Italy. ^[2] MIFT Department, University of Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy. ^[3] NSE Department, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. ^[4] MIFT Department, University of Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy. Electronic address: mallamaced@unime.it. ^[5]

关键词 Aqueous solutions Biological interactions Hydrogen bonding Thermodynamic state functions