Synthesis of Axially Chiral CF<sub>3</sub> -Substituted 2-Arylpyrroles by Sequential Phosphine-Catalyzed Asymmetric [3+2] Annulation and Oxidative Central-to-Axial Chirality Transfer.

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作者： Chuan,Xiang Alvin Tan ^[1] ; Rui,Li ^[2] ; Fuhao,Zhang ^[1] ; Lei,Dai ^[3] ; Nisar,Ullah ^[1] ; Yixin,Lu ^[1]

作者单位： Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore. ^[1] Integrative Sciences & Engineering Programme (ISEP), National University of Singapore, 28 Medical Drive, Singapore, 117456, Singapore. ^[2] Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, Fujian 350207, China. ^[3] Chemistry Department, King Fahd University of Petroleum & Minerals, Dhahran, 31261, Saudi Arabia. ^[4]

关键词 Atroposelectivity Axial Chirality Chirality Transfer Phosphine Catalysis [3+2] Annulation

主题词催化作用(Catalysis);磷化氢类(Phosphines);立体异构现象(Stereoisomerism);氧化性应激(Oxidative Stress)

DOI 10.1002/anie.202209494

PMID 36200408

发布时间 2022-12-20

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