Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral α-Difluoromethylamines from Ketimines.

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第一作者： Qinghe,Liu

第一单位： Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai 200032, China.

作者： Qinghe,Liu ^[1] ; Taige,Kong ^[1] ; Chuanfa,Ni ^[1] ; Jinbo,Hu ^[1]

作者单位： Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai 200032, China. ^[1]

关键词 difluoromethylation fluorine ketimine nucleophilic addition sulfoximine

主题词指示剂和试剂(Indicators and Reagents);立体异构现象(Stereoisomerism);亚胺类(Imines);胺类(Amines)

DOI 10.3390/molecules27207076

PMID 36296670

发布时间 2022-10-30

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