In-situ Kinetic Studies of Rh(II)-Catalyzed C-H Functionalization to Achieve High Catalyst Turnover Numbers.

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第一作者： Bo,Wei

第一单位： Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States.

作者： Bo,Wei ^[1] ; Jack C,Sharland ^[1] ; Donna G,Blackmond ^[2] ; Djamaladdin G,Musaev ^[1] ; Huw M L,Davies ^[3]

作者单位： Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States. ^[1] Department of Chemistry, The Scripps Research Institute, La Jolla, California, 92037, United States. ^[2] Cherry L. Emerson Center for Scientific Computation, Emory University, 1521 Dickey Drive, Atlanta, Georgia 30322, United States. ^[3]

关键词 C—H functionalization DFT calculations High turnover numbers Low catalyst loading additive effects rhodium-carbene

DOI 10.1021/acscatal.2c04115

PMID 37274060

发布时间 2023-11-05

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