Arsenite oxidase in complex with antimonite and arsenite oxyanions: Insights into the catalytic mechanism.

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第一作者： Filipa,Engrola

第一单位： UCIBIO - Applied Molecular Biosciences Unit, Department of Chemistry, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal; Associate Laboratory i4HB - Institute for Health and Bioeconomy, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal.

作者： Filipa,Engrola ^[1] ; Márcia A S,Correia ^[1] ; Cameron,Watson ^[2] ; Carlos C,Romão ^[3] ; Luis F,Veiros ^[4] ; Maria João,Romão ^[5] ; Teresa,Santos-Silva ^[6] ; Joanne M,Santini ^[7]

作者单位： UCIBIO - Applied Molecular Biosciences Unit, Department of Chemistry, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal; Associate Laboratory i4HB - Institute for Health and Bioeconomy, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal. ^[1] Division of Biosciences, Institute of Structural and Molecular Biology, University College London, London, United Kingdom. ^[2] ITQB NOVA, NOVA University Lisbon, Oeiras, Portugal. ^[3] Centro de Química Estrutural, Institute of Molecular Sciences, Lisboa, Portugal; Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Lisboa, Portugal. ^[4] UCIBIO - Applied Molecular Biosciences Unit, Department of Chemistry, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal; Associate Laboratory i4HB - Institute for Health and Bioeconomy, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal. Electronic address: mjr@fct.unl.pt. ^[5] UCIBIO - Applied Molecular Biosciences Unit, Department of Chemistry, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal; Associate Laboratory i4HB - Institute for Health and Bioeconomy, School of Science and Technology, NOVA University Lisbon, Caparica, Portugal. Electronic address: tsss@fct.unl.pt. ^[6] Division of Biosciences, Institute of Structural and Molecular Biology, University College London, London, United Kingdom. Electronic address: j.santini@ucl.ac.uk. ^[7]

关键词 DFT calculations X-ray crystallography antimony arsenic arsenite oxidase enzyme mechanism molybdenum enzyme

主题词人类(Humans);锑(Antimony);砷(Arsenic);亚砷酸盐类(Arsenites);氧化还原(Oxidation-Reduction)

DOI 10.1016/j.jbc.2023.105036

PMID 37442232

发布时间 2023-09-06

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