首页> Angewandte Chemie (International ed. in English)> Cl3Al-PH3 Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes.

Cl3Al-PH3 Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes.

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第一作者： Jan,Oswald

第一单位： Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5/10, Zürich, 8093, Switzerland.

作者： Jan,Oswald ^[1] ; Csilla,Fekete ^[2] ; Matt,Baker ^[1] ; Mark,Bispinghoff ^[1] ; Paul G,Pringle ^[3] ; Norbert,Weferling ^[4] ; Zoltán,Benkő ^[5] ; Hansjörg,Grützmacher ^[6]

作者单位： Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5/10, Zürich, 8093, Switzerland. ^[1] Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Műegyetem rakpart 3, Budapest, 1111, Hungary. ^[2] School of Chemistry, University of Bristol, Bristol, BS81TS, UK. ^[3] WefConsult GmbH, 50354, Hürth, Germany. ^[4] Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Műegyetem rakpart 3, Budapest, 1111, Hungary.;HUN-REN-BME, Computation Driven Chemistry Research Group, Műegyetem rakpart 3, Budapest, 1111, Hungary. ^[5] Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5/10, Zürich, 8093, Switzerland.;LIFM, IGCME, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510006, China. ^[6]

关键词 Aluminum Lewis pair Phosphine Reaction mechanism Substitution

DOI 10.1002/anie.202501656

PMID 40129366

发布时间 2025-06-08

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