Layered P2-Na0.7MnO2.05 microflakes as a cathode material for high performance sodium-ion batteries
Layered P2-Na0.7MnO2.05 microflakes as a cathode material for high performance sodium-ion batteries
摘要Sodium-ion batteries (SIBs),as the low-cost and large-scale energy storage devices,have attracted wide attention,but their capacity and cycle performance are limited by cathode materials.Here,P2-Na0.7MnO2.05 microflakes with the diameter 500 nm to 1 μm are synthesized by an improved solid-state reaction.The as-prepared P2-Na0.7 MnO2.05 microflakes exhibit excellent electrochemical performance when tested as a cathode material of SIBs.It delivers a considerably reversible capacity of 142.7 mA h g-1 at a current density of 0.3 C (1C =180 mA g-1) with a slow capacity decay to 121.5 mA h g-1 after 50 cycles.Even at a high current density of 2 C,the P2-Na0.7MnO2.05 microflakes still show a specific capacity of 88.9 mA h g-1 with a capacity retention of 75% after 100 cycles.The above performance of Na0.7MnO2.05 microflakes are better than Na0.7MnO2.05 with large block morphology,which is mainly attributed to the lamellar morphology of P2-Na0.7 MnO2.05 alleviating structural deformation and accelerating reaction kinetics.This strategy will provide new opportunities to develop stable oxide cathodes for SIBs.
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